It is a major mineral component of eclogite along with pyrope garnet and also occurs in blueschist facies and UHP (ultrahigh-pressure) metamorphic rocks. It also occurs in eclogite xenoliths from kimberlite as well as in crustal rocks metamorphosed at high pressures. Associated minerals in eclogites include garnet, quartz or coesite, rutile, kyanite, phengite, and lawsonite. Minerals such as glaucophane, lawsonite, titanite, and epidote occur with omphacite in blueschist facies metamorphic rocks. The name "jade," usually referring to rocks made of jadeite, is sometimes also applied to rocks consisting entirely of omphacite.
The name "omphacite" has been applied to compositions that contain between 20% and 80% jadeite. The stability of intermediate compositions between augite and jadeite is not well-understood, but miscibility gaps appear to be present at temperatures below 300 °C to 400 °C, and perhaps at higher temperatures. Pairs of pyroxenes -- both augite plus omphacite and omphacite plus jadeite -- appear to have existed in equilibrium at low temperatures.
It was first described in 1815 in the Münchberg Metamorphic complex, Franconia, Bavaria, Germany. The name omphacite derives from the Greek omphax or unripe grape for the typical green color.